全固态电池卤化物固态电解质研究进展

李宏晓; 胡兆兴; 张肖梅; 田瑞雪; 卞刘振; 安胜利

doi:10.19799/j.cnki.2095-4239.2025.0970

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全固态电池卤化物固态电解质研究进展

储能材料与器件 | 更新时间：2026-04-29

- 全固态电池卤化物固态电解质研究进展
- Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery
- 储能科学与技术 2026年15卷第4期页码：1205-1218
- 作者机构：
  
  1.内蒙古科技大学稀土产业学院
  2.内蒙古科技大学材料科学与工程学院
  3.轻稀土资源绿色提取与高效利用教育部重点实验室(内蒙古科技大学)
  4.内蒙古先进陶瓷材料与器件重点实验室，内蒙古包头 014010
- 作者简介：
  
  李宏晓（1998—），女，硕士研究生，研究方向为卤化物固态电解质，E-mail：lihongxiao1021@163.com；
  安胜利，教授，研究方向为固体氧化物燃料电池，E-mail：san@imust.edu.cn。
- 基金信息：
  
  内蒙古自治区自然科学基金青年基金资助项目(2024QN05029);内蒙古自治区直属高校基本科研业务费资助项目(2024QNJS018);2023年度自治区本级事业单位引进高层次人才科研支持(0701012408)
- DOI：10.19799/j.cnki.2095-4239.2025.0970
  中图分类号： TM 911.3
- 收稿：2025-10-28，
  
  修回：2025-11-18，
  
  纸质出版：2026-04-28
- 稿件说明：
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李宏晓, 胡兆兴, 张肖梅, 等. 全固态电池卤化物固态电解质研究进展[J]. 储能科学与技术, 2026, 15(4): 1205-1218.

LI Hongxiao, HU Zhaoxing, ZHANG Xiaomei, et al. Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery[J]. Energy Storage Science and Technology, 2026, 15(4): 1205-1218.
李宏晓, 胡兆兴, 张肖梅, 等. 全固态电池卤化物固态电解质研究进展[J]. 储能科学与技术, 2026, 15(4): 1205-1218. DOI： 10.19799/j.cnki.2095-4239.2025.0970.

LI Hongxiao, HU Zhaoxing, ZHANG Xiaomei, et al. Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery[J]. Energy Storage Science and Technology, 2026, 15(4): 1205-1218. DOI： 10.19799/j.cnki.2095-4239.2025.0970.

摘要

本文聚焦于卤化物固态电解质这一近年来快速发展且极具潜力的新兴体系，围绕其材料分类、合成路径及性能优化策略展开系统综述，旨在为其规模化应用所面临的关键问题提供思路与技术参考。首先，本文梳理了卤化物固态电解质的发展历程，归纳了不同结构类型的主要特点，并比较了其在离子电导率、力学性能及环境稳定性等方面的差异。在合成方法方面，重点介绍了3类具有实际应用前景的制备工艺，系统分析了各自的适用条件、工艺特点及局限性。在性能优化策略方面，本文重点讨论了通过元素掺杂、锂位含量调控以及构建复合电解质等手段提升材料离子电导率与电化学稳定性的效果，并阐述了其内在作用机制。进一步地，本文总结了当前卤化物固态电解质在空气敏感性、界面稳定性、成本控制及规模化制备等方面仍面临的瓶颈，并展望了未来可能的发展方向，如新型卤化物体系探索、AI辅助材料设计、先进表征技术及理论模拟等。本文旨在通过对现有研究成果的系统梳理与深入分析，为卤化物固态电解质领域的后续研究提供理论支撑与技术借鉴，推动其在高安全和高能量密度全固态电池中的实际应用进程。

Abstract

This study focuses on halide solid electrolytes

an emerging system that has rapidly developed and shows great potential in recent years. It systematically reviews their material classification

synthesis routes

and performance optimization strategies

providing insights and technical references to address key challenges in their large-scale application. First

the development history of halide solid electrolytes is outlined

main characteristics of different structural types are summarized

and differences in their ionic conductivity

mechanical properties

and environmental stability are compared. In terms of synthesis

three preparation methods with practical application prospects are highlighted

with systematic analysis of their applicable conditions

process features

and limitations. For performance optimization

effective approaches to enhance material ionic conductivity and electrochemical stability through element doping

lithium content regulation

and composite electrolyte construction are discussed

along with their underlying mechanisms. Current bottlenecks

including air sensitivity

interface stability

cost control

and scalable production

are summarized. Future directions

such as exploring new halide systems

AI-assisted material design

advanced characterization techniques

and theoretical simulations

are proposed. Through systematic review and in-depth analysis

this rveiew provides theoretical support and technical guidance for further research in the field of halide solid electrolytes

promoting their practical application in high-safety

high-energy-density all-solid-state batteries.

关键词

Keywords

references

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