层状/橄榄石混合正极材料的研究进展：从机制协同到性能增强

朱瑾; 张小颂; 左秀霞; 易金; 刘小瑜; 夏永高

doi:10.19799/j.cnki.2095-4239.2026.0230

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层状/橄榄石混合正极材料的研究进展：从机制协同到性能增强

储能材料与器件 | 更新时间：2026-08-26

- 层状/橄榄石混合正极材料的研究进展：从机制协同到性能增强
- Research progress of layered/olivine blended cathodes materials: from mechanism synergy to performance enhancement
- 储能科学与技术 2026年15卷第8期页码：3054-3070
- 作者机构：
  
  1.上海大学理学院，上海 200444
  2.中国科学院宁波材料技术与工程研究所，浙江宁波 315201
  3.中国科学院大学材料科学与光电工程中心，北京 100049
  4.宁波工程学院新能源学院，浙江宁波 315336
- 作者简介：
  
  朱瑾（2001—），女，硕士研究生，研究方向为锂离子电池，E-mail：zhujin@nimte.ac.cn；
  张小颂，助理研究员，研究方向为锂离子电池，E-mail：zhangxiaosong@nimte.ac.cn
  刘小瑜，副教授，研究方向为锂离子电池，E-mail：xiaoyuliu@shu.edu.cn。
- 基金信息：
  
  高稳定锰基复合正极材料开发与工程化（国家重点研发计划）(2022YFB2404401)
- DOI：10.19799/j.cnki.2095-4239.2026.0230
  中图分类号： TM 911
- 收稿：2026-03-23，
  
  修回：2026-04-15，
  
  网络首发：2026-08-26，
  
  纸质出版：2026-08-28
- 稿件说明：
移动端阅览
朱瑾, 张小颂, 左秀霞, 等. 层状/橄榄石混合正极材料的研究进展: 从机制协同到性能增强[J]. 储能科学与技术, 2026, 15(8): 3054-3070.

ZHU Jin, ZHANG Xiaosong, ZUO Xiuxia, et al. Research progress of layered/olivine blended cathodes materials: from mechanism synergy to performance enhancement[J]. Energy Storage Science and Technology, 2026, 15(8): 3054-3070.
朱瑾, 张小颂, 左秀霞, 等. 层状/橄榄石混合正极材料的研究进展: 从机制协同到性能增强[J]. 储能科学与技术, 2026, 15(8): 3054-3070. DOI： 10.19799/j.cnki.2095-4239.2026.0230.

ZHU Jin, ZHANG Xiaosong, ZUO Xiuxia, et al. Research progress of layered/olivine blended cathodes materials: from mechanism synergy to performance enhancement[J]. Energy Storage Science and Technology, 2026, 15(8): 3054-3070. DOI： 10.19799/j.cnki.2095-4239.2026.0230.

摘要

正极材料是决定锂离子电池性能上限的核心组分，但单一正极材料难以兼顾储能电池对能量密度、循环寿命、成本、安全性以及环境适应性等的多维度需求。层状/橄榄石混合正极材料通过复合高能量密度的层状氧化物与高安全性、长循环寿命的橄榄石磷酸盐材料，在保留各组分固有优势的基础上实现性能互补，成为突破这一技术瓶颈的有效策略。本文系统综述了层状/橄榄石混合正极材料的研究进展。首先简单介绍层状和橄榄石材料各自的晶体结构特征和电化学行为特点，重点探讨两类材料在颗粒尺寸匹配与电压平台兼容性方面的关键问题。其次，简单概述了层状/橄榄石混合正极材料的发展历程，并总结了混合正极的两种主要制备方式。进一步，从界面稳定、结构强化与动力学优化三个层面揭示混合体系的协同作用机制，阐明该类材料在抑制界面副反应、缓解有害相变以及提升电化学反应动力学等方面的核心作用。上述三类机制相互关联、互为支撑，共同构筑协同增强效应，从而实现混合体系综合性能的协同提升。最后，结合当前储能技术的发展趋势，展望该类材料在大规模储能及固态电池等新型电池体系中的发展潜力，并梳理其深化研究方向和未来发展需求，以期为下一代高性能储能电池的发展提供材料支撑与理论参考。

Abstract

Cathode materials are critical to determining the upper performance limit of lithium-ion batteries. However

single cathode materials cannot meet the multidimensional requirements of energy storage systems in terms of energy density

cycle life

cost

safety

and environmental adaptability. Layered/olivine blended cathode materials combine the high energy density of layered oxides with the high safety and long cycle life olivine phosphate materials

achieving performance complementarity while retaining the intrinsic advantages of each component. As a result

they have become an effective strategy for overcoming this technical bottleneck.This paper systematically reviews recent progress in layered/olivine blended cathode materials. First

it briefly summarizes the crystal structure characteristics and electrochemical behaviors of layered oxides and olivine phosphates. Based on this foundation

it examines key issues such as particle size matching and voltage platform compatibility when these two materials are combined. It also outlines the development history and briefly describes two typical preparation strategies for layered/olivine blended cathode materials. Furthermore

the synergistic mechanisms of the blended system are analyzed from three aspects: interface stability

structural reinforcement

and kinetic optimization. The core contributions of this strategy in suppressing interfacial side reactions

alleviating detrimental phase transitions

and enhancing electrochemical reaction kinetics are also discussed. Specifically

the olivine component helps regulate and stabilize the interfacial behavior of layered materials through physical isolation and interfacial modulation across contact interfaces

active regions

and film-forming layers. Owing to their rigid polyanion framework

these materials provide multidimensional structural reinforcement to the blended system at the atomic

grain

and electrode scales. At the same time

by forming a kinetic synergy with layered materials

they significantly improve the electrochemical reaction kinetics of the electrode in terms of structural basis

thermodynamic equilibrium

and dynamic process. It should be noted that these three mechanisms do not operate in isolation; rather

they interact through coupling and feedback regulation to form a multiscale synergistic enhancement effect

thereby significantly improving the overall electrochemical performance of the blended system.Finally

in view of current energy storage trends

this review discusses the potential of this type of material system in large-scale energy storage and emerging battery systems such as solid-state batteries

summarizing future research directions and development requirements the aim of providing material support and theoretical guidance for next-generation high-performance energy storage batteries.

关键词

Keywords

references

DUNN B, KAMATH H, TARASCON J M. Electrical energy storage for the grid: A battery of choices[J]. Science, 2011, 334(6058): 928-935. DOI:10.1126/science.1212741.

LUO X, WANG J H, DOONER M, et al. Overview of current development in electrical energy storage technologies and the application potential in power system operation[J]. Applied Energy, 2015, 137: 511-536. DOI:10.1016/j.apenergy.2014. 09.081.

ZHANG X, LIU S Q, WANG B Y, et al. Mn-based cathode materials for rechargeable batteries[J]. Science China Chemistry, 2024, 67(1): 87-105. DOI:10.1007/s11426-023-1706-8.

SONG J, WANG H C, ZUO Y X, et al. Building better full manganese-based cathode materials for next-generation lithium-ion batteries[J]. Electrochemical Energy Reviews, 2023, 6(1): 20. DOI:10.1007/s41918-023-00184-8.

KESHARI N, DEWANGAN T, BASU K, et al. Next-generation high-voltage cathodes for lithium-ion batteries: Challenges, innovations, and future directions[J]. Advanced Sustainable Systems, 2025, 9(10): e00543. DOI:10.1002/adsu.202500543.

ZHANG S S. Problems and their origins of Ni-rich layered oxide cathode materials[J]. Energy Storage Materials, 2020, 24: 247-254. DOI:10.1016/j.ensm.2019.08.013.

ZHANG C X, JIANG W J, HE W T, et al. Heteroepitaxial interface of layered cathode materials for lithium ion batteries[J]. Energy Storage Materials, 2021, 37: 161-189. DOI:10.1016/j.ensm. 202 1.02.009.

SHURTZ R C, HEWSON J C. Review—Materials science predictions of thermal runaway in layered metal-oxide cathodes: A review of thermodynamics[J]. Journal of the Electrochemical Society, 2020, 167(9): 090543. DOI:10.1149/1945-7111/ab8fd9.

KHAN A, AL RASHID H, ROY P K, et al. Challenges and the way to improve lithium-ion battery technology for next-generation energy storage[J]. Energy & Environmental Materials, 2025, 8(6): e70088. DOI:10.1002/eem2.70088.

SHARMA M, ALHOLAISI A A, ALSHAHRANI M D, et al. Advances in lithium-ion batteries: Graphene anodes and lithium iron phosphate cathodes[J]. Ionics, 2025, 31(12): 12523-12544. DOI:10.1007/s11581-025-06798-w.

HEUBNER C, LIEBMANN T, SCHNEIDER M, et al. Recent insights into the electrochemical behavior of blended lithium insertion cathodes: A review[J]. Electrochimica Acta, 2018, 269: 745-760. DOI:10.1016/j.electacta.2018.02.165.

NUMATA T, AMEMIYA C, KUMEUCHI T, et al. Advantages of blending LiNi 0.8 Co 0.2 O 2 into Li 1+ x Mn 2- x O 4 cathodes[J ] . Journal of Power Sources, 2001, 97: 358-360. DOI:10.1016/S0378-7753(01)00753-4.

WEN L, SHI Y, YE L W, et al. Progress of lithium manganese iron phosphate in blended cathode materials[J]. Materials Science and Engineering: R: Reports, 2025, 164: 100952. DOI:10.1016/j.mser.2025.100952.

MOHAMED N, ALLAM N K. Recent advances in the design of cathode materials for Li-ion batteries[J]. RSC Advances, 2020, 10(37): 21662-21685. DOI:10.1039/d0ra03314f.

KHALID R, SHAH A, JAVED M, et al. Progress and obstacles in electrode materials for lithium-ion batteries: A journey towards enhanced energy storage efficiency[J]. RSC Advances, 2025, 15(20): 15951-15998. DOI:10.1039/d5ra02042e.

YANG L Y, YANG K, ZHENG J X, et al. Harnessing the surface structure to enable high-performance cathode materials for lithium-ion batteries[J]. Chemical Society Reviews, 2020, 49(14): 4667-4680. DOI:10.1039/d0cs00137f.

YANG Q, HUANG J, LI Y J, et al. Surface-protected LiCoO 2 with ultrathin solid oxide electrolyte film for high-voltage lithium ion batteries and lithium polymer batteries[J ] . Journal of Power Sources, 2018, 388: 65-70. DOI:10.1016/j.jpowsour.2018.03.076.

CHEN Y B, SONG S L, ZHANG X Q, et al. The challenges, solutions and development of high energy Ni-rich NCM/NCA LiB cathode materials[J]. Journal of Physics: Conference Series, 2019, 1347(1): 012012. DOI:10.1088/1742-6596/1347/1/012012.

YAO Y, ZHANG Z, ZHENG Y Q, et al. Recent advances in coating strategies for lithium-rich manganese-based layered oxide cathodes[J]. Journal of Energy Storage, 2025, 134: 118132. DOI:10.1016/j.est.2025.118132.

YAMADA A, KUDO Y, LIU K Y. Reaction mechanism of the olivine-type Li x (Mn 0.6 Fe 0.4 )PO 4 (0≤ x ≤1)[J ] . Journal of the Electrochemical Society, 2001, 148(7): A747. DOI:10.1149/1.137 5167.

LIU X S, WANG Y J, BARBIELLINI B, et al. Why LiFePO 4 is a safe battery electrode: Coulomb repulsion induced electron-state reshuffling upon lithiation[J ] . Physical Chemistry Chemical Physics, 2015, 17(39): 26369-26377. DOI:10.1039/c5cp04739k.

ANANSUKSAWAT N, SANGSANIT T, PREMPLUEM S, et al. How uniform particle size of NMC90 boosts lithium ion mobility for faster charging and discharging in a cylindrical lithium ion battery cell[J]. Chemical Science, 2024, 15(6): 2026-2036. DOI:10.1039/d3sc05698h.

ZHANG J, QIAO J S, SUN K N, et al. Balancing particle properties for practical lithium-ion batteries[J]. Particuology, 2022, 61: 18-29. DOI:10.1016/j.partic.2021.05.006.

LIU J Y, CHEN S, KONG D W, et al. Interaction between LMFP and NCMA and its effect on blending cathode-based cells[J]. Energies, 2024, 17(4): 808. DOI:10.3390/en17040808.

LING J, KARUPPIAH C, KRISHNAN S G, et al. Phosphate polyanion materials as high-voltage lithium-ion battery cathode: A review[J]. Energy & Fuels, 2021, 35(13): 10428-10450.

BESNARD N, ETIEMBLE A, DOUILLARD T, et al. Multiscale morphological and electrical characterization of charge transport limitations to the power performance of positive electrode blends for lithium-ion batteries[J]. Advanced Energy Materials, 2017, 7(8): 1602239. DOI:10.1002/aenm.201602239.

HUANG J D, YANG Y X, LIU Y X, et al. Lithium hexamethyldisilazide endows Li||NCM811 battery with superior performance[J]. Nano-Micro Letters, 2023, 15(1): 33. DOI:10.10 07/s40820-022-00998-z.

WANG J M, WEI J, LIANG D, et al. Dual-coating strategy enhances high-voltage capacity and cycling stability of Ni-rich NCM811 cathodes[J]. Electrochimica Acta, 2026, 546: 147755. DOI:10.1016/j.electacta.2025.147755.

LIN C, LI J Y, YIN Z W, et al. Structural understanding for high-voltage stabilization of lithium cobalt oxide[J]. Advanced Materials, 2024, 36(6): 2307404. DOI:10.1002/adma.202307404.

ZHENG J M, MYEONG S, CHO W, et al. Li- and Mn-rich cathode materials: Challenges to commercialization[J]. Advanced Energy Materials, 2017, 7(6): 1601284. DOI:10.1002/aenm.201601284.

CHATZOGIANNAKIS D, ARSZELEWSKA V, CABELGUEN P E, et al. Understanding charge transfer dynamics in blended positive electrodes for Li-ion batteries[J]. Energy Storage Materials, 2024, 69: 103414. DOI:10.1016/j.ensm.2024.103414.

KIM H S, KONG M Z, KIM K, et al. Electrochemical characteristics of LiFePO 4 /LiCoO 2 mixed electrode for Li secondary battery[J ] . Journal of Electroceramics, 2009, 23(2): 219-224. DOI:10.1007/s10832-007-9403-0.

ZHANG H S, LI X N, LIU W F, et al. Olivine LiFePO 4 as an additive into LiCoO 2 electrodes for LIBs to improve high-voltage performances[J ] . Journal of Alloys and Compounds, 2021, 869: 159188. DOI:10.1016/j.jallcom.2021.159188.

YAN Y W, ZH ENG Y C, ZHANG H T, et al. Blending layered cathode with olivine: An economic strategy for enhancing the structural and thermal stability of 4.65 V LiCoO 2 [J ] . Advanced Functional Materials, 2023, 33(43): 2304496. DOI:10.1002/adfm. 202304496.

YOU L Z, TANG J T, WU Q, et al. LiFePO 4 -coated LiNi 0.6 Co 0.2 Mn 0.2 O 2 for lithium-ion batteries with enhanced cycling performance at elevated temperatures and high voltages[J ] . RSC Advances, 2020, 10(62): 37916-37922. DOI:10.1039/d0ra07764j.

ZHANG X, HOU M Y, TAMIRATE A G, et al. Carbon coated nano-sized LiMn 0.8 Fe 0.2 PO 4 porous microsphere cathode material for Li-ion batteries[J ] . Journal of Power Sources, 2020, 448: 227438. DOI:10.1016/j.jpowsour.2019.227438.

ZHANG B C, XIE X M, PENG Z D, et al. Synthesis of flexible LiMn 0.8 Fe 0.2 PO 4 /C microsphere and its synergetic effects with blended LiNi 0.85 Co 0.10 Al 0.05 O 2 electrodes[J ] . Journal of Power Sources, 2022, 541: 231671. DOI:10.1016/j.jpowsour.2022.23 1671.

WEI H X, UNIVERSITY C S, et al. Li-rich Mn-based/lithium iron phosphate composite cathode material with excellent electrochemical performance enabled by cooperative shunting mechanism[J]. ACS Applied Energy Materials, 2025, 8(11): 7497-7507. DOI:10.1021/acsaem.5c00818.

HAN C, WU J H, LI S Q, et al. Suppressing the voltage decay of Li 1.2 Mn 0.6 Ni 0.2 O 2 cathode materials enabled by LiMn 0.8 Fe 0.2 PO 4 /C for long-cycling lithium-ion batteries[J ] . Solid State Ionics, 2021, 364: 115629. DOI:10.1016/j.ssi.2021.115629.

LEISING R A, TAKEUCHI E S. Mixed cathode material for high energy density electrochemical cells: EP0999604[P]. 2000-05-10.

BARKER J, SAIDI M Y, KELLEY T E. Electrodes comprising mixed active particles: US20040197654[P]. 2004-10-07.

WANG H, ZHANG W D, ZHU L Y, et al. Effect of LiFePO 4 coating on electrochemical performance of LiCoO 2 at high temperature[J ] . Solid State Ionics, 2007, 178(1/2): 131-136. DOI:10.1016/j.ssi.2006.10.028.

WHITACRE J F, ZAGHIB K, WEST W C, et al. Dual active material composite cathode structures for Li-ion batteries[J]. Journal of Power Sources, 2008, 177(2): 528-536. DOI:10.1016/j.jpowsour.2007.11.076.

GALLAGHER K G, KANG S H, PARK S U, et al. x Li 2 MnO 3 ·(1- x )LiMO 2 blended with LiFePO 4 to achieve high energy density and pulse power capability[J ] . Journal of Power Sources, 2011, 196(22): 9702-9707. DOI:10.1016/j.jpowsour.2011.07.054.

PARK T J, KANG S H, KIM C, et al. Electrochemical properties of LiNi 0.90 Co 0.05 Al 0.05 O 2 /LiFe 0.9 Mn 0.1 PO 4 /C blended cathode for lithium ion batteries[J ] . Chemistry Letters, 2013, 42(10): 1320-1322. DOI:10.1246/cl.130542.

YUE M, AIKEN C, DESHMUKH J, et al. Improved elevated temperature performance of LiFePO 4 /graphite cell by blending NMC640 in cathode[J ] . Journal of the Electrochemical Society, 2023, 170(11): 110532. DOI:10.1149/1945-7111/ad0bab.

HEUBNER C, LIEBMANN T, LÄMMEL C, et al. Internal dynamics of blended Li-insertion electrodes[J]. Journal of Energy Storage, 2018, 20: 101-108. DOI:10.1016/j.est.2018.09.003.

ALLAHYARI E, GHORBANZADEH M, RIAHIFAR R, et al. Electrochemical performance of NCM/LFP/Al composite cathode materials for lithium-ion batteries[J]. Materials Research Express, 2018, 5(5): 055503. DOI:10.1088/2053-1591/aac0c7.

DAWKINS J I G, PAN Y N, GHAVIDEL M Z, et al. Exploring the synergistic effects of dual-layer electrodes for high power Li-ion batteries[J]. ChemElectroChem, 2023, 10(21): e202300279. DOI:10.1002/celc.202300279.

BISHT A, DIXIT M, ESSEHLI R, et al. Assessing the coating implications of slurry formulations in NCMA and LFMP blend cathodes for lithium-ion batteries[J]. Journal of Power Sources, 2025, 640: 236734. DOI:10.1016/j.jpowsour.2025.236734.

ZHAO X X, AN L W, SUN J C, et al. LiNi 0.5 Co 0.2 Mn 0.3 O 2 -LiMn 0.6 Fe 0.4 PO 4 mixture with both excellent electrochemical performance and low cost as cathode material for power lithium ion batteries[J ] . Journal of the Electrochemical Society, 2018, 165(2): A142-A148. DOI:10.1149/2.0431802jes.

KIM S B, LEE K J, CHOI W J, et al. Preparation and cycle performance at high temperature for Li[Ni 0.5 Co 0.2 Mn 0.3 ] O 2 coated with LiFePO 4 [J ] . Journal of Solid State Electrochemistry, 2010, 14(6): 919-922. DOI:10.1007/s10008-009-0873-7.

ZHENG F H, YANG C H, XIONG X H, et al. Nanoscale surface modification of lithium-rich layered-oxide composite cathodes for suppressing voltage fade[J]. Angewandte Chemie International Edition, 2015, 54(44): 13058-13062. DOI:10.1002/anie.20150 6408.

LIU S Q, WANG Y L, XIAO D D, et al. Mn-based layered/olivine composite-structure cathode for long-life lithium-ion batteries[J]. Energy Storage Materials, 2025, 76: 104151. DOI:10.1016/j.ensm.2025.104151.

NA S, PARK C, PARK K. LiFePO 4 (LFP) coating and blending on Li 1.05 (Ni 0.88 Co 0.08 Mn 0.04 )O 2 (Ni-rich NCM): A strategy for reduced gas generation[J ] . Journal of Alloys and Compounds, 2025, 1031: 180771. DOI:10.1016/j.jallcom.2025.180771.

HONG Z W, DONG H C, HAN S J, et al. Nail penetration-safe LiNi 0.6 Co 0.2 Mn 0.2 O 2 pouch cells enabled by LiMn 0.7 Fe 0.3 PO 4 cathode safety additive[J ] . Journal of Power Sources, 2021, 512: 230505. DOI:10.1016/j.jpowsour.2021.230505.

ZHONG Z Q, CHEN L Z, ZHU C B, et al. Nano LiFePO 4 coated Ni rich composite as cathode for lithium ion batteries with high thermal ability and excellent cycling performance[J ] . Journal of Power Sources, 2020, 464: 228235. DOI:10.1016/j.jpowsour. 2020.228235.

HU Q, HE Y F, REN D S, et al. Targeted masking enables stable cycling of LiNi 0.6 Co 0.2 Mn 0.2 O 2 at 4.6 V[J ] . Nano Energy, 2022, 96: 107123. DOI:10.1016/j.nanoen.2022.107123.

SIM R, SU L S, DOLOCAN A, et al. Delineating the impact of transition-metal crossover on solid-electrolyte interphase formation with ion mass spectrometry[J]. Advanced Materials, 2024, 36(14): 2311573. DOI:10.1002/adma.202311573.

YANG J, PARK S, LEE S, et al. High-voltage deprotonation of layered-type materials as a newly identified cause of electrode degradation[J]. Journal of Materials Chemistry A, 2023, 11(6): 3018-3027. DOI:10.1039/d2ta07496f.

ALAGIA V E, MOHANAKUMAR S, DUITS M H G, et al. Influence of anions on the formation of a passivating Fe-rich interfacial layer during olivine dissolution[J]. Geochimica et Cosmochimica Acta, 2025, 403: 152-165. DOI:10.1016/j.gca.2025.06.012.

KIM E, KIM J H, CHANG J H, et al. Decoupling activation from passivation in high-rate Li-rich Mn-based layered oxides through the construction of a conductive LiFePO 4 island architecture[J ] . Journal of Power Sources, 2026, 671: 239599. DOI:10.1016/j.jpowsour.2026.239599.

TIAN S Z, LIU S Q, DU H Z, et al. Layered/olivine composite structure-induced stable gradient interfacial chemistry toward high-temperature lithium-ion batteries[J]. ACS Nano, 2024, 18(46): 32065-32076.

ANDERSSON A S, KALSKA B, HÄGGSTRÖM L, et al. Lithium extraction/insertion in LiFePO 4 : An X-ray diffraction and Mössbauer spectroscopy study[J ] . Solid State Ionics, 2000, 130(1/2): 41-52. DOI:10.1016/S0167-2738(00)00311-8.

KUO L Y, GUILLON O, KAGHAZCHI P. Origin of structural phase transitions in Ni-rich Li x Ni 0.8 Co 0.1 Mn 0.1 O 2 with lithiation/delithiation: A first-principles study[J ] . ACS Sustainable Chemistry & Engineering, 2021, 9(22): 7437-7446.

LIU H, WOLFMAN M, KARKI K, et al. Intergranular cracking as a major cause of long-term capacity fading of layered cathodes[J]. Nano Letters, 2017, 17(6): 3452-3457.

LIU J Z, DONG J Y, WANG M, et al. Redox-active stabilizer-enhanced structural and thermal stability of Ni-rich cathodes via an economical blending strategy[J ] . eTransportation, 2025, 24: 100428. DOI:10.1016/j.etran.2025.100428.

ZHANG H L, LIU H, PIPER L F J, et al. Oxygen loss in layered oxide cathodes for Li-ion batteries: Mechanisms, effects, and mitigation[J]. Chemical Reviews, 2022, 122(6): 5641-5681.

ZHU L, YAN T F, JIA D, et al. LiFePO 4 -coated LiNi 0.5 Co 0.2 Mn 0.3 O 2 cathode materials with improved high voltage electrochemical performance and enhanced safety for lithium ion pouch cells[J ] . Journal of the Electrochemical Society, 2019, 166(3): A5437-A5444. DOI:10.1149/2.0651903jes.

ZHANG Z G, QU Y L, LI Y D, et al. Mechanical regulation of Ni-rich cathode to "the golden mean" towards safe Li-ion batteries during nail penetration[J]. Energy Storage Materials, 2024, 73: 103802. DOI:10.1016/j.ensm.2024.103802.

ABAZA A, FERRARI S, WONG H K, et al. Experimental study of internal and external short circuits of commercial automotive pouch lithium-ion cells[J]. Journal of Energy Storage, 2018, 16: 211-217. DOI:10.1016/j.est.2018.01.015.

WEI H R, WANG H B, LIU L J, et al. Ion-electron synergistic effect and cathode self-charge behavior of hybrid cathode[J]. Energy Storage Materials, 2026, 86: 104920. DOI:10.1016/j.ensm.2026.104920.

LEE S, SCANLAN K, REED S, et al. Cost-effective layered oxide-olivine blend cathodes for high-rate pulse power lithium-ion batteries[J]. Advanced Energy Materials, 2025, 15(5): 2403002. DOI:10.1002/aenm.202403002.

KANG M, OH S, AHN K, et al. Unlocking the potential of internal Li-ion transfer in Ni-rich cathodes blended with LiFePO 4 to address first cycle irreversible capacity loss and degradation[J ] . Energy & Environmental Science, 2025, 18(16): 7950-7966. DOI:10.1039/d5ee00404g.

PARK Y J, HAN J, et al. Parasitic high-voltage effects on the degradation of LiMn 0.75 Fe 0.25 PO 4 cathodes in Li-ion batteries[J ] . Chemistry of Materials, 2026, 38(1): 351-361. DOI:10.1021/acs.chemmater.5c02532.

ZHU Z X, JIANG T L, ALI M, et al. Rechargeable batteries for grid scale energy storage[J]. Chemical Reviews, 2022, 122(22): 16610-16751.

CAO W Z, ZHANG J N, LI H. Batteries with high theoretical energy densities[J]. Energy Storage Materials, 2020, 26: 46-55. DOI:10.1016/j.ensm.2019.12.024.

HUANG Q Q, LIU J Q, CHEN X M, et al. Recent progress and challenges of Li-rich Mn-based cathode materials for solid-state lithium-ion batteries[J]. Advanced Materials, 2025, 37(5): 2410006. DOI:10.1002/adma.202410006.

TRIPOLITI E K, DOBSON D P, FORTES A D, et al. Structure and thermal expansion of end-member olivines I: Crystal and magnetic structure, thermal expansion, and spontaneous magnetostriction of synthetic fayalite, Fe 2 SiO 4 , determined by high-resolution neutron powder diffraction[J ] . Mineralogical Magazine, 2023, 87(6): 789-806. DOI:10.1180/mgm.2023.66.

LIU G B, LI S M, MEI J, et al. New insights into low temperature properties of Li-rich layered cathode materials[J]. Journal of Power Sources, 2017, 353: 51-57. DOI:10.1016/j.jpowsour.2017. 04.004.

XU L, TANG S, CHENG Y, et al. Interfaces in solid-state lithium batteries[J]. Joule, 2018, 2(10): 1991-2015. DOI:10.1016/j.joule.2018.07.009.

OH H, et al. Bimodal composite cathodes advancing the chemo-mechanical integrity and kinetics for all-solid-state batteries[J]. ACS Energy Letters, 2026, 11(2): 2103-2114. DOI:10.1021/acsenergylett.5c03923.

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