高倍率赝电容储钠材料与钠离子电容器

燕泽锐; 魏湫龙

doi:10.19799/j.cnki.2095-4239.2026.0168

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高倍率赝电容储钠材料与钠离子电容器

超级电容器关键材料与器件专刊 | 更新时间：2026-07-01

- 高倍率赝电容储钠材料与钠离子电容器
- High rate pseudocapacitive materials toward sodium-ion capacitors
- 储能科学与技术 2026年15卷第5期页码：1797-1811
- 作者机构：
  
  厦门大学材料学院，福建厦门 361005
- 作者简介：
  
  燕泽锐（1999—），女，博士研究生，研究方向为高性能钠离子电容器的设计开发，E-mail：20720240156369@stu.xmu.edu.cn；
  魏湫龙，副教授，研究方向为高比能与高功率电化学储能材料与器件，E-mail：qlwei@xmu.edu.cn。
- 基金信息：
  
  国家自然科学基金(22479123;22179113)
- DOI：10.19799/j.cnki.2095-4239.2026.0168
  中图分类号： TM 911;TM 53
- 收稿：2026-02-26，
  
  修回：2026-03-31，
  
  纸质出版：2026-05-28
- 稿件说明：
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燕泽锐, 魏湫龙. 高倍率赝电容储钠材料与钠离子电容器[J]. 储能科学与技术, 2026, 15(5): 1797-1811.

YAN Zerui, WEI Qiulong. High rate pseudocapacitive materials toward sodium-ion capacitors[J]. Energy Storage Science and Technology, 2026, 15(5): 1797-1811.
燕泽锐, 魏湫龙. 高倍率赝电容储钠材料与钠离子电容器[J]. 储能科学与技术, 2026, 15(5): 1797-1811. DOI： 10.19799/j.cnki.2095-4239.2026.0168.

YAN Zerui, WEI Qiulong. High rate pseudocapacitive materials toward sodium-ion capacitors[J]. Energy Storage Science and Technology, 2026, 15(5): 1797-1811. DOI： 10.19799/j.cnki.2095-4239.2026.0168.

摘要

赝电容储钠材料凭借高比容量和高倍率性能的综合电化学特性，对实现兼具高功率与高能量密度的钠离子电容器具有重要应用价值。本文系统综述了赝电容材料的电荷存储机制、电化学性能及其动力学特性，并总结了基于赝电容储钠材料所组装钠离子电容器的研究进展。重点围绕钛基、钒基、锰基等典型赝电容储钠材料的储钠机制、结构调控与电化学性能之间的构效关系展开讨论，深化对赝电容材料“储钠机制-性能协同”规律的理解，创新提出了“高容量电池型正极-高倍率赝电容负极”的新型混合器件设计方案，进而推动实现钠离子电容器在高功率密度下的高能量密度以及长循环寿命性能。最后，面向未来高功率需求场景，对高性能钠离子电容器的产业化发展方向作出展望。

Abstract

Pseudocapacitive sodium ion storage materials

characterized by their combined high specific capacity and superior rate capability

are of significant value for the realization of sodium-ion capacitors with both high power and high energy density. This review systematically summarizes the charge storage mechanisms

electrochemical performance

and kinetic characteristics of pseudocapacitive materials

and provides an overview of the research progress in sodium-ion capacitors assembled using pseudocapacitive materials. The discussion primarily focuses on the structure-activity relationships between sodium ion storage mechanisms

structural regulation

and electrochemical performance intypical pseudocapacitive materials such as titanium-based

vanadium-based

and manganese-based. By deepening the understanding of the "sodium ion storage mechanism-performance synergy" in pseudocapacitive materials

this review innovatively proposes an advanced hybrid device design that couples high capacity battery-type positive electrodes with high-rate pseudocapacitive negative electrodes

thereby promoting the achievement of high energy density at high power densities and long cycle life in sodium-ion capacitors. Finally

an outlook on the future industrialization of high-performance sodium-ion capacitors is presented

targeting the demands of high-power application scenarios.

关键词

Keywords

references

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