Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery

LI Hongxiao; HU Zhaoxing; ZHANG Xiaomei; TIAN Ruixue; BIAN Liuzhen; AN Shengli

doi:10.19799/j.cnki.2095-4239.2025.0970

您当前的位置：

首页 >

文章列表页 >

Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery

Energy Storage Materials and Devices | 更新时间：2026-07-01

- Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery
- Energy Storage Science and Technology Vol. 15, Issue 4, Pages: 1205-1218(2026)
- 作者机构：
  
  1.内蒙古科技大学稀土产业学院
  2.内蒙古科技大学材料科学与工程学院
  3.轻稀土资源绿色提取与高效利用教育部重点实验室(内蒙古科技大学)
  4.内蒙古先进陶瓷材料与器件重点实验室，内蒙古包头 014010
- 作者简介：
- 基金信息：
- DOI：10.19799/j.cnki.2095-4239.2025.0970
  CLC： TM 911.3
- Received：28 October 2025，
  
  Revised：2025-11-18，
  
  Published：28 April 2026
- 稿件说明：
移动端阅览
李宏晓, 胡兆兴, 张肖梅, 等. 全固态电池卤化物固态电解质研究进展[J]. 储能科学与技术, 2026, 15(4): 1205-1218.

LI Hongxiao, HU Zhaoxing, ZHANG Xiaomei, et al. Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery[J]. Energy Storage Science and Technology, 2026, 15(4): 1205-1218.
李宏晓, 胡兆兴, 张肖梅, 等. 全固态电池卤化物固态电解质研究进展[J]. 储能科学与技术, 2026, 15(4): 1205-1218. DOI： 10.19799/j.cnki.2095-4239.2025.0970.

LI Hongxiao, HU Zhaoxing, ZHANG Xiaomei, et al. Research progress on solid-state halide electrolytes for all-solid-state lithium-ion battery[J]. Energy Storage Science and Technology, 2026, 15(4): 1205-1218. DOI： 10.19799/j.cnki.2095-4239.2025.0970.

摘要

本文聚焦于卤化物固态电解质这一近年来快速发展且极具潜力的新兴体系，围绕其材料分类、合成路径及性能优化策略展开系统综述，旨在为其规模化应用所面临的关键问题提供思路与技术参考。首先，本文梳理了卤化物固态电解质的发展历程，归纳了不同结构类型的主要特点，并比较了其在离子电导率、力学性能及环境稳定性等方面的差异。在合成方法方面，重点介绍了3类具有实际应用前景的制备工艺，系统分析了各自的适用条件、工艺特点及局限性。在性能优化策略方面，本文重点讨论了通过元素掺杂、锂位含量调控以及构建复合电解质等手段提升材料离子电导率与电化学稳定性的效果，并阐述了其内在作用机制。进一步地，本文总结了当前卤化物固态电解质在空气敏感性、界面稳定性、成本控制及规模化制备等方面仍面临的瓶颈，并展望了未来可能的发展方向，如新型卤化物体系探索、AI辅助材料设计、先进表征技术及理论模拟等。本文旨在通过对现有研究成果的系统梳理与深入分析，为卤化物固态电解质领域的后续研究提供理论支撑与技术借鉴，推动其在高安全和高能量密度全固态电池中的实际应用进程。

Abstract

This study focuses on halide solid electrolytes

an emerging system that has rapidly developed and shows great potential in recent years. It systematically reviews their material classification

synthesis routes

and performance optimization strategies

providing insights and technical references to address key challenges in their large-scale application. First

the development history of halide solid electrolytes is outlined

main characteristics of different structural types are summarized

and differences in their ionic conductivity

mechanical properties

and environmental stability are compared. In terms of synthesis

three preparation methods with practical application prospects are highlighted

with systematic analysis of their applicable conditions

process features

and limitations. For performance optimization

effective approaches to enhance material ionic conductivity and electrochemical stability through element doping

lithium content regulation

and composite electrolyte construction are discussed

along with their underlying mechanisms. Current bottlenecks

including air sensitivity

interface stability

cost control

and scalable production

are summarized. Future directions

such as exploring new halide systems

AI-assisted material design

advanced characterization techniques

and theoretical simulations

are proposed. Through systematic review and in-depth analysis

this rveiew provides theoretical support and technical guidance for further research in the field of halide solid electrolytes

promoting their practical application in high-safety

high-energy-density all-solid-state batteries.

关键词

Keywords

references

GOODENOUGH J B. How we made the Li-ion rechargeable battery[J]. Nature Electronics, 2018, 1(3): 204. DOI:10.1038/s41928-018-0048-6.

MANTHIRAM A, YU X W, WANG S F. Lithium battery chemistries enabled by solid-state electrolytes[J]. Nature Reviews Materials, 2017, 2: 16103. DOI:10.1038/natrevmats.2016.103.

李枫, 程晓斌, 罗锦达, 等. 金属氯化物固态电解质及其全固态电池研究现状与展望[J]. 储能科学与技术, 2024, 13(1): 193-211. DOI:10.19799/j.cnki.2095-4239.2023.0821.

LI F, CHENG X B, LUO J D, et al. Metal chloride solid-state electrolytes and all-solid-state batteries: State-of-the-art developments and perspectives[J]. Energy Storage Science and Technology, 2024, 13(1): 193-211. DOI:10.19799/j.cnki.2095-4239.2023.0821.

CHEN R S, LI Q H, YU X Q, et al. Approaching practically accessible solid-state batteries: Stability issues related to solid electrolytes and interfaces[J]. Chemical Reviews, 2020, 120(14): 6820-6877.

WEISS M, SIMON F J, BUSCHE M R, et al. From liquid- to solid-state batteries: Ion transfer kinetics of heteroionic interfaces[J]. Electrochemical Energy Reviews, 2020, 3(2): 221-238. DOI:10.1007/s41918-020-00062-7.

万峰, 闫迎春, 范壮军. 卤化物固态电解质研究进展与展望[J]. 无机盐工业, 2024, 56(11): 15-29. DOI:10.19964/j.issn.1006-4990.2024-0077.

WAN F, YAN Y C, FAN Z J. Research progress and prospect of halide solid electrolytes[J]. Inorganic Chemicals Industry, 2024, 56(11): 15-29. DOI:10.19964/j.issn.1006-4990.2024-0077.

ZHANG J, JIN J, SHENG O W, et al. Achieving higher critical current density in LGPS-based lithium metal batteries via a synergistic interlayer for physical inhibition and chemical scavenging of lithium dendrites[J ] . ACS Applied Materials & Interfaces, 2024, 16(44): 60376-60386.

WU J H, SHEN L, ZHANG Z H, et al. All-solid-state lithium batteries with sulfide electrolytes and oxide cathodes[J]. Electrochemical Energy Reviews, 2021, 4(1): 101-135. DOI:10.1007/s41918-020-00081-4.

MA Z, XUE H G, GUO S P. Recent achievements on sulfide-type solid electrolytes: Crystal structures and electrochemical performance[J]. Journal of Materials Science, 2018, 53(6): 3927-3938. DOI:10.1007/s10853-017-1827-6.

WANG L C, WU J X, BAO C S, et al. Interfacial engineering for high-performance garnet-based solid-state lithium batteries[J]. SusMat, 2024, 4(1): 72-105. DOI:10.1002/sus2.187.

HAN F D, ZHU Y Z, HE X F, et al. Electrochemical stability of Li 10 GeP 2 S 12 and Li 7 La 3 Zr 2 O 12 solid electrolytes[J ] . Advanced Energy Materials, 2016, 6(8): 1501590. DOI:10.1002/aenm.201 501590.

LI X N, LIANG J W, YANG X F, et al. Progress and perspectives on halide lithium conductors for all-solid-state lithium batteries[J]. Energy & Environmental Science, 2020, 13(5): 1429-1461.

TUO K Y, YIN F S, MI F H, et al. Elucidating the diffusion pathway of lithium ions in superionic halide solid electrolytes Li 2+ x Hf 1- x In x Cl 6 for all-solid-state lithium-metal based b atteries[J ] . Journal of Energy Chemistry, 2023, 87: 12-23. DOI:10.1016/j.jechem.2023.08.016.

GINNINGS D C, PHIPPS T E. Temperature-conductance curves of solid salts. Ⅲ. halides of lithium[J]. Journal of the American Chemical Society, 1930, 52(4): 1340-1345.

LIANG C C, EPSTEIN J, BOYLE G H. A high-voltage, solid-state battery system[J]. Journal of the Electrochemical Society, 1969, 116(10): 1452. DOI:10.1149/1.2411560.

WEPPNER W, HUGGINS R A. Ionic conductivity of alkali metal chloroaluminates[J]. Physics Letters A, 1976, 58(4): 245-248. DOI:10.1016/0375-9601(76)90087-6.

WEPPNER W, HUGGINS R A. Ionic conductivity of solid and liquid LiAlCl 4 [J ] . Journal of the Electrochemical Society, 1977, 124(1): 35-38. DOI:10.1149/1.2133238.

KANNO R, TAKEDA Y, TAKADA K, et al. Ionic conductivity and phase transition of the spinel system Li 2–2 x M 1+ x Cl 4 (M=Mg, Mn, Cd)[J ] . Journal of the Electrochemical Society, 1984, 131(3): 469-474. DOI:10.1149/1.2115611.

KANNO R, TAKEDA Y, YAMAMOTO O. Structure, ionic conductivity and phase transformation of double chloride spinels[J]. Solid State Ionics, 1988, 28: 1276-1281. DOI:10.1016/0167-2738(88)90370-0.

ASANO T, SAKAI A, OUCHI S, et al. Solid halide electrolytes with high lithium-ion conductivity for application in 4 V class bulk-type all-solid-state batteries[J]. Advanced Materials, 2018, 30(44): 1803075. DOI:10.1002/adma.201803075.

LI X N, LIANG J W, CHEN N, et al. Water-mediated synthesis of a superionic halide solid electrolyte[J]. Angewandte Chemie International Edition, 2019, 58(46): 16427-16432. DOI:10.1002/anie.201909805.

LI X N, LIANG J W, LUO J, et al. Air-stable Li 3 InCl 6 electrolyte with high voltage compatibility for all-solid-state batteries[J ] . Energy & Environmental Science, 2019, 12(9): 2665-2671.

WANG K, REN Q Y, GU Z Q, et al. A cost-effective and humidity-tolerant chloride solid electrolyte for lithium batteries[J]. Nature Communications, 2021, 12: 4410. DOI:10.1038/s41467-021-24697-2.

LIU X K, ZHOU Y X, MI F H, et al. Superionic halide solid electrolyte Li 1.7 Zr 0.7 Ta 0.3 Cl 6 for durable all-solid-state lithium batteries[J ] . Energy Storage Materials, 2024, 72: 103737. DOI:10.1016/j.ensm.2024.103737.

LEI P, WU G, LIU H, et al. Boosting ion conduction and moisture stability through Zn 2+ substitution of chloride el ectrolytes for all-solid-state lithium batteries[J ] . Advanced Energy Materials, 2025, 15(24): 2405760. DOI:10.1002/aenm.202405760.

欧慧婷, 郑佳宜, 彭钇雄, 等. 固态电解质的国内外研究进展[J]. 化工设计通讯, 2024, 50(9): 1-5. DOI:10.3969/j.issn.1003-6490.2024.09.001.

OU H T, ZHENG J Y, PENG Y X, et al. Research progress of solid electrolyte at home and abroad[J]. Chemical Engineering Design Communications, 2024, 50(9): 1-5. DOI:10.3969/j.issn.1003-6490.2024.09.001.

EMLY A, KIOUPAKIS E, VAN DER VEN A. Phase stability and transport mechanisms in antiperovskite Li 3 OCl and Li 3 OBr superionic conductors[J ] . Chemistry of Materials, 2013, 25(23): 4663-4670.

BACHMAN J C, MUY S, GRIMAUD A, et al. Inorganic solid-state electrolytes for lithium batteries: Mechanisms and properties governing ion conduction[J]. Chemical Reviews, 2016, 116(1): 140-162.

LIANG J W, VAN DER MAAS E, LUO J, et al. A series of ternary metal chloride superionic conductors for high-performance all-solid-state lithium batteries[J]. Advanced Energy Materials, 2022, 12(21): 2103921. DOI:10.1002/aenm.202103921.

WANG C H, LIANG J W, KIM J T, et al. Prospects of halide-based all-solid-state batteries: From material design to practical application[J]. Science Advances, 2022, 8(36): eadc9516. DOI:10.1126/sciadv.adc9516.

TYAGI A K, KÖHLER J, BALOG P, et al. Syntheses and structures of Li 3 ScF 6 and high pressure LiScF 4 -, luminescence properties of LiScF 4 , a new phase in the system LiF-ScF 3 [J ] . Journal of Solid State Chemistry, 2005, 178(9): 2620-2625. DOI:10.1016/j.jssc.2005.04.038.

CHOI B, MOON B, SEO H, et al. Dielectric and ionic conduction properties in LiYF 4 single crystals[J ] . Materials & Design, 2000, 21(6): 567-570. DOI:10.1016/S0261-3069(00)00023-6.

LIANG J W, LI X N, WANG S, et al. Site-occupation-tuned superionic Li x ScCl 3+ x halide solid electrolytes for all-solid-state batteries[J ] . Journal of the American Chemical Society, 2020, 142(15): 7012-7022. DOI:10.1021/jacs.0c00134.

KUSKE P, SCHÄFER W, LUTZ H D. Neutron diffraction studies on spinel type Li 2 ZnCl 4 [J ] . Materials Research Bulletin, 1988, 23(12): 1805-1808. DOI:10.1016/0025-5408(88)90192-4.

LI X N, LIANG J W, KIM J T, et al. Highly stable halide-electrolyte-based all-solid-state Li-Se batteries[J]. Advanced Materials, 2022, 34(20): 2200856. DOI:10.1002/adma.202200856.

BOHNS ACK A, STENZEL F, ZAJONC A, et al. Ternäre halogenide vom typ A3MX6. VI [1 ] . ternäre chloride der selten-erd-elemente mit lithium, Li 3 MCl 6 (M=Tb, Lu, Y, Sc): Synthese, kristallstrukturen und ionenbewegung[J ] . Zeitschrift für Anorganische und Allgemeine Chemie, 1997, 623(7): 1067-1073. DOI:10.1002/zaac.19976230710.

LUTZ H D, PFITZNER A, COCKCROFT J K. Structural phase transition and nonstoichiometry of Li 2 FeCl 4 -Neutron diffraction studies[J ] . Journal of Solid State Chemistry, 1993, 107(1): 245-249. DOI:10.1006/jssc.1993.1344.

LI F, CHENG X B, LU L L, et al. Stable all-solid-state lithium metal batteries enabled by machine learning simulation designed halide electrolytes[J]. Nano Letters, 2022, 22(6): 2461-2469.

YIN Y C, YANG J T, LUO J D, et al. A LaCl 3 -based lithium superionic conductor compatible with lithium metal[J ] . Nature, 2023, 616(7955): 77-83. DOI:10.1038/s41586-023-05899-8.

SENDEK A, CUBUK E D, ANTONIUK E R, et al. Machine learning-assisted discovery of solid Li-ion conducting materials[J]. Chemistry of Materials, 2019, 31(2): 342-352.

HÖNLE W, HETTICH B, SIMON A. Darstellung und kristallstrukturen von LiGaCl 4 und LiGaI 4 /preparation and crystal structure of LiGaCL 4 and LiGaI 4 [J ] . Zeitschrift für Naturforschung B, 1987, 42(2): 248-250. DOI:10.1515/znb-1987-0222.

TOMITA Y, OHKI H, YAMADA K, et al. Ionic conductivity and structure of halo complex salts of group 13 elements[J]. Solid State Ionics, 2000, 136: 351-355. DOI:10.1016/S0167-2738(00)00491-4.

LIU Y S, WANG S, NOLAN A M, et al. Tailoring the cation lattice for chloride lithium-ion conductors[J]. Advanced Energy Materials, 2020, 10(40): 2002356. DOI:10.1002/aenm.20200 2356.

OI T, MIYAUCHI K. Amorphous thin film ionic conductors of m LiF. n AlF 3 [J ] . Materials Research Bulletin, 1981, 16(10): 1281-1289. DOI:10.1016/0025-5408(81)90099-4.

ZEVGOLIS A, WOOD B C, MEHMEDOVIĆ Z, et al. Alloying effects on superionic conductivity in lithium indium halides for all-solid-state batteries[J]. APL Materials, 2018, 6(4): 047903. DOI:10.1063/1.5011378.

LIU Z T, MA S, LIU J, et al. High ionic conductivity achieved in Li 3 Y(Br 3 Cl 3 ) mixed halide solid electrolyte via promoted diffusion pathways and enhanced grain boundary[J ] . ACS Energy Letters, 2021, 6(1): 298-304.

TOMITA Y, FUJI-I A, OHKI H, et al. New lithium ion conductor Li 3 InBr 6 studied by 7 Li NMR[J ] . Chemistry Letters, 1998, 27(3): 223-224. DOI:10.1246/cl.1998.223.

TOMITA Y, MATSUSHITA H, KOBAYASHI K, et al. Substitution effect of ionic conductivity in lithium ion conductor, LI 3 INBR 6- x Cl x [J ] . Solid State Ionics, 2008, 179(21/22/23/24/25/26): 867-870. DOI:10.1016/j.ssi.2008.02.012.

FU J M, WANG S, WU D J, et al. Halide heterogeneous structure boosting ionic diffusion and high-voltage stability of sodium superionic conductors[J]. Advanced Materials, 2024, 36(3): 2308012. DOI:10.1002/adma.202308012.

HARTWIG P, WEPPNER W, WICHELHAUS W, et al. Lithium nitride halides—New solid electrolytes with high Li + ion conductivity[J ] . Angewandte Chemie International Edition in English, 1980, 19(1): 74-75. DOI:10.1002/anie.198000741.

OBAYASHI H, GOTOH A, NAGAI R. Composition dependence of lithium ionic conductivity in lithium nitride-lithium iodide system[J]. Materials Research Bulletin, 1981, 16(5): 581-585. DOI:10.1016/0025-5408(81)90124-0.

WEPPNER W, HARTWIG P, RABENAU A. Consideration of lithium nitride halides as solid electrolytes in practical galvanic cell applications[J]. Journal of Power Sources, 1981, 6(3): 251-259. DOI:10.1016/0378-7753(81)80030-4.

LI W H, LI M S, CHI EN P H, et al. Lithium-compatible and air-stable vacancy-rich Li 9 N 2 Cl 3 for high-areal capacity, long-cycling all-solid-state lithium metal batteries[J ] . Science Advances, 2023, 9(42): eadh4626. DOI:10.1126/sciadv.adh4626.

ZHAO Y S, DAEMEN L L. Superionic conductivity in lithium-rich anti-perovskites[J]. Journal of the American Chemical Society, 2012, 134(36): 15042-15047.

FANG H, JENA P. Li-rich antiperovskite superionic conductors based on cluster ions[J]. Proceedings of the National Academy of Sciences of the United States of America, 2017, 114(42): 11046-11051. DOI:10.1073/pnas.1704086114.

WANG Q T, LIU D X, MA X F, et al. Cl-doped Li 10 SnP 2 S 12 with enhanced ionic conductivity and lower Li-ion migration barrier[J ] . ACS Applied Materials & Interfaces, 2022, 14(19): 22225-22232.

MUY S, VOSS J, SCHLEM R, et al. High-throughput screening of solid-state Li-ion conductors using lattice-dynamics descriptors[J]. iScience, 2019, 16: 270-282. DOI:10.1016/j.isci.2019.05.036.

SCHLEM R, MUY S, PRINZ N, et al. Mechanochemical synthesis: A tool to tune cation site disorder and ionic transport properties of Li 3 MCl 6 (M=Y, Er) superionic conductors[J ] . Advanced Energy Materials, 2020, 10(6): 1903719. DOI:10.1002/aenm.201903719.

YU C, LI Y, ADAIR K R, et al. Tuning ionic conductivity and electrode compatibility of Li 3 YBr 6 for high-performance all solid-state Li batteries[J ] . Nano Energy, 2020, 77: 105097. DOI:10.1016/j.nanoen.2020.105097.

SCHLEM R, GHIDIU M, CULVER S P, et al. Changing the static and dynamic lattice effects for the improvement of the ionic transport properties within the argyrodite Li 6 PS 5– x Se x I[J ] . ACS Applied Energy Materials, 2020, 3(1): 9-18. DOI:10.1021/acsaem.9b01794.

SCHLEM R, BANIK A, OHNO S, et al. Insights into the lithium sub-structure of superionic conductors Li 3 YCl 6 and Li 3 YBr 6 [J ] . Chemistry of Materials, 2021, 33(1): 327-337.

ZHAO B, LU Y F, YUAN B H, et al. Preparation of free-standing Li 3 InCl 6 solid electrolytes film with infiltration-method enable roll-to-roll manufacture[J ] . Materials Letters, 2022, 310: 131463. DOI:10.1016/j.matlet.2021.131463.

WANG C H, LIANG J W, LUO J, et al. A universal wet-chemistry synthesis of solid-state halide electrolytes for all-solid-state lithium-metal batteries[J]. Science Advances, 2021, 7(37): eabh1896. DOI:10.1126/sciadv.abh1896.

YAN J, BI L N, SUN T R, et al. Wet chemical synthesis of dianion-doped halide solid-state electrolytes for improved interface stability[J]. Journal of Power Sources, 2025, 633: 236424. DOI:10.1016/j.jpowsour.2025.236424.

XIE J, SENDEK A D, CUBUK E D, et al. Atomic layer deposition of stable LiAlF 4 lithium ion conductive interfacial layer for stable cathode cycling[J ] . ACS Nano, 2017, 11(7): 7019-7027.

FU J M, WANG C H, WANG S, et al. A cost-effective all-in-one halide material for all-solid-state batteries[J]. Nature, 2025, 643(8070): 111-118. DOI:10.1038/s41586-025-09153-1.

JEON H J, SUBRAMANIAN Y, RYU K S. Variation of electrochemical performance of Li 2 ZrCl 6 halide solid electrolyte with Mn substitution for all-solid-state batteries[J ] . Journal of Power Sources, 2024, 602: 234343. DOI:10.1016/j.jpowsour. 2024.234343.

GAO K N, BAI F, SUN Z, et al. Aliovalent substitution of Al 3+ in Li 2 ZrCl 6 solid electrolyte towards large-scale application[J ] . Energy Storage Materials, 2024, 70: 103444. DOI:10.1016/j.ensm.2024.103444.

LEI M, LI B, YIN R R, et al. Superior Li-ion transport in LiNb 0.5 Ta 0.5 Cl 6 [J ] . Advanced Functional Materials, 2024, 34(51): 2410509. DOI:10.1002/adfm.202410509.

LI C, ZENG Z C, ZHANG W S, et al. Exploring tetra-/penta-/ hexavalent ion substitution in yttrium-based halide solid-state electrolytes[J]. Nano Letters, 2025, 25(5): 1792-1799.

JIA Q X, YAO Z J, XIANG J Y, et al. Rare earth metal ion-doped halide solid electrolytes plus Ta 5+ substitution for long cycling all-solid-state batteries[J ] . Advanced Functional Materials, 2025, 35(22): 2426053. DOI:10.1002/adfm.202426053.

WANG W Z, JING K X, MA H, et al. Simultaneously enhance humidity tolerance and ionic conductivity of halide electrolytes by cation-anion co-doping[J]. Small, 2025, 21(21): 2500943. DOI:10.1002/smll.202500943.

ZHANG H C, YU Z Z, CHEN H N, et al. Li-richening strategy in Li 2 ZrCl 6 lattice towards enhanced ionic conductivity[J ] . Journal of Energy Chemistry, 2023, 79: 348-356. DOI:10.1016/j.jechem. 2023.01.008.

HELM B, SCHLEM R, WANKMILLER B, et al. Exploring aliovalent substitutions in the lithium halide superionic conductor Li 3- x In 1- x Zr x Cl 6 (0≤ x ≤0.5)[J ] . Chemistry of Materials, 2021, 33(12): 4773-4782.

WANG C H, WANG S, LIU X D, et al. New insights into aliovalent substituted halide solid electrolytes for cobalt-free all-solid state batteries[J]. Energy & Environmental Science, 2023, 16(11): 5136-5143.

WANG S H, XU X W, CUI C, et al. Air sensitivity and degradation evolution of halide solid state electrolytes upon exposure[J]. Advanced Functional Materials, 2022, 32(7): 2108805. DOI:10.1002/adfm.202108805.

WANG K, GU Z Q, LIU H X, et al. High-humidity-tolerant chloride solid-state electrolyte for all-solid-state lithium batteries[J]. Advanced Science, 2024, 11(14): 2305394. DOI:10.1002/advs. 202305394.

LIU H, LI Y, DONG C X, et al. Fluorinated coating stabilizing halide solid electrolytes for all-solid-state lithium metal batteries[J]. Energy Storage Materials, 2025, 75: 104107. DOI:10.1016/j.ensm.2025.104107.

KIM K T, WOO J, KIM Y S, et al. Ultrathin superhydrophobic coatings for air-stable inorganic solid electrolytes: Toward dry room application for all-solid-state batteries[J]. Advanced Energy Materials, 2023, 13(43): 2301600. DOI:10.1002/aenm.20230 1600.

SHAO Q N, YAN C H, GAO M X, et al. New insights into the effects of Zr substitution and carbon additive on Li 3- x Er 1- x Zr x Cl 6 halide solid electrolytes[J ] . ACS Applied Materials & Interfaces, 2022, 14(6): 8095-8105. DOI:10.1021/acsami.1c25087.

ZHANG S M, ZHAO F P, WANG S, et al. Advanced high-voltage all-solid-state Li-ion batteries enabled by a dual-halogen solid electrolyte[J]. Advanced Energy Materials, 2021, 11(32): 2100836. DOI:10.1002/aenm.202100836.

FU J Z, JIN W T, YANG S G, et al. In-situ formation of stable interface towards Li-in anode for halide solid-state electrolyte[J ] . Materials Today, 2025, 90: 143-153. DOI:10.1016/j.mattod.2025. 08.038.

TANG W, XIA W, HUSSAIN F, et al. A dual-halogen electrolyte for protective-layer-free all-solid-state lithium batteries[J]. Journal of Power Sources, 2023, 568: 232992. DOI:10.1016/j.jpowsour. 2023.232992.

CAO M F, PAN L, WANG Y P, et al. Insight into the interfacial evolutions between halide and sulfide solid electrolytes[J]. ACS Energy Letters, 2025, 10(11): 5336-5344.

Views

191

下载量

CSCD

Alert me when the article has been cited

提交

Tools

Publicity Resources

Recent advances in structural design and ion transport of lithium-ion battery materials under magnetic field regulation

Design of high efficiency digital LDO circuit in compressed air energy storage

Machine learning-assisted phase-field simulation for predicting the impact of lithium-ion transport parameters on maximum battery dendrite height and space utilization rate

Preparation and performance of a flame-retardant gel polymer electrolyte

Energy efficiency analysis of vertical gravity energy storage systems

Related Author

BIAN Liuzhen

AN Shengli

SUN Jiabao

LI Yue

XU Hanghang

ZHANG Rui

WANG Xingai

WANG Ning

Related Institution

Key Laboratory of Green Extraction and Efficient Utilization of Light Rare-Earth Resources (Inner Mongolia University of Science and Technology),Ministry of Education

State Key Laboratory of Intelligent Power Distribution Equipment and System, Hebei University of Technology

School of Electrical Engineering, Hebei University of Technology

Pingdingshan Polytechnic College

School of Materials Science and Engineering, Shanghai University

⁰