1.哈尔滨工业大学,黑龙江 哈尔滨 150000
2.军事科学院某所,北京 100141
3.西南石油 大学,四川 成都 610500
4.中国科学院大连化学物理研究所,辽宁 大连 116023
5.中国 科学院上海应用物理研究所,上海 201800
鲍正洋(2001—),男,博士在读,研究方向:PEM体系高效氧电极催化剂研究,E-mail:1102865649@qq.com;
孔凡鹏,副教授,研究方向:质子交换膜燃料电池及电解水制氢,E-mail:fpkong@hit.edu.cn
邵志刚,研究员,研究方向:燃料电池及电解水制氢,E-mail:zhgshao@dicp.ac.cn。
收稿:2026-08-03,
修回:2026-08-30,
网络首发:2026-09-05,
移动端阅览
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在“双碳”目标牵引下,风电、光伏等可再生能源快速发展,离网绿电制氢已成为提升绿电消纳和推动绿氢规模化制备的重要路径。然而,可再生能源波动会直接传递至电解槽,使电解过程由额定稳态转向宽功率、强瞬态和频繁切换运行,并对气体安全、传质传热、界面稳定性和寿命提出更高要求。本文围绕波动电源与电解槽动态运行窗口匹配,构建低负荷安全适应性、高负荷承载能力、动态爬坡能力、启停灵活性和规模化经济性五维评价框架,比较碱性电解水(AWE)、质子交换膜电解水(PEMWE)、阴离子交换膜电解水(AEMWE)和固体氧化物电解水(SOEC)的运行特征、关键材料、动态适配机制及工程边界。分析表明,AWE成本低、规模化基础好,但受液态电解液、多孔隔膜和气液两相传输限制;PEMWE负荷范围宽、响应快,但贵金属和钛基组件成本较高;AEMWE兼具低成本和柔性潜力,仍需突破膜电极动态寿命瓶颈;SOEC更适合稳定热源耦合下的高效制氢与共电解转化。在此基础上,进一步从功率预测与储能缓冲、多类型电解槽协同运行以及储氢/氨醇耦合消纳等方面提出发展方向,为离网绿电条件下电解水制氢技术优化与规模化发展提供参考。
Driven by China's carbon peaking and carbon neutrality goals
renewable energy sources such as wind and solar power have developed rapidly. Off-grid green electricity-to-hydrogen production has become an important pathway for improving renewable electricity utilization and enabling large-scale green hydrogen production. However
in the absence of external power buffering
renewable power fluctuations are directly transmitted to electrolyzers
shifting electrolysis from rated steady-state operation to wide-load
highly transient
and frequently switching conditions. This imposes higher requirements on gas safety
mass and heat transfer
interfacial stability
and lifetime. This review focuses on the matching between fluctuating power input and the dynamic operating window of electrolyzers. A five-dimensional evaluation framework is established
including low-load safety adaptability
high-load tolerance
dynamic ramping capability
start-stop flexibility
and scalability/economic viability. Based on this framework
the operating characteristics
key materials
dynamic adaptation mechanisms
and engineering boundaries of alkaline water electrolysis (AWE)
proton exchange membrane water electrolysis (PEMWE)
anion exchange membrane water electrolysis (AEMWE)
and solid oxide electrolysis cells (SOEC) are compared. The analysis shows that AWE offers low cost and strong scalability
but is limited by liquid electrolytes
porous diaphragms
and gas-liquid two-phase transport. PEMWE enables a wide load range and fast response
but is constrained by the high cost of noble metals and titanium-based components. AEMWE has the potential to combine low cost with flexible operation
but still requires breakthroughs in the dynamic lifetime of membrane electrode assemblies. SOEC is more suitable for high-efficiency hydrogen production and co-electrolysis when coupled with stable heat sources. Furthermore
an integrated off-grid green hydrogen system of "source-storage-electrolyzer-hydrogen/chemical conversion" is proposed by combining power forecasting
energy storage buffering
coordinated operation of multiple electrolyzer types
and hydrogen/ammonia/methanol utilization.
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