一维钒基纳米材料在水系锌离子电池中的研究进展

刘杰; 尹伟; 张秀秀; 音正龙; 周惠敏

doi:10.19799/j.cnki.2095-4239.2026.0361

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一维钒基纳米材料在水系锌离子电池中的研究进展

储能材料与器件 | 更新时间：2026-08-26

- 一维钒基纳米材料在水系锌离子电池中的研究进展
- A review on one-dimensional vanadium-based nanomaterials for aqueous zinc-ion batteries
- 储能科学与技术 2026年15卷第8期页码：3110-3130
- 作者机构：
  
  新疆大学新疆智能与绿色纺织重点实验室，新疆乌鲁木齐 830046
- 作者简介：
  
  刘杰（2002—），男，硕士研究生，研究方向为纱线电极及柔性储能器件的制备，E-mail：13610625824@163.com；
  周惠敏，副教授，硕士生导师，研究方向主要为纳米纤维复合材料的功能化应用以及柔性储能器件的开发，E-mail：xjzhouhuimin@126.com。
- 基金信息：
  
  国家自然科学基金青年基金(22305206)
- DOI：10.19799/j.cnki.2095-4239.2026.0361
  中图分类号： TM 02
- 收稿：2026-04-28，
  
  修回：2026-05-29，
  
  网络首发：2026-08-26，
  
  纸质出版：2026-08-28
- 稿件说明：
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刘杰, 尹伟, 张秀秀, 等. 一维钒基纳米材料在水系锌离子电池中的研究进展[J]. 储能科学与技术, 2026, 15(8): 3110-3130.

LIU Jie, YIN Wei, ZHANG Xiuxiu, et al. A review on one-dimensional vanadium-based nanomaterials for aqueous zinc-ion batteries[J]. Energy Storage Science and Technology, 2026, 15(8): 3110-3130.
刘杰, 尹伟, 张秀秀, 等. 一维钒基纳米材料在水系锌离子电池中的研究进展[J]. 储能科学与技术, 2026, 15(8): 3110-3130. DOI： 10.19799/j.cnki.2095-4239.2026.0361.

LIU Jie, YIN Wei, ZHANG Xiuxiu, et al. A review on one-dimensional vanadium-based nanomaterials for aqueous zinc-ion batteries[J]. Energy Storage Science and Technology, 2026, 15(8): 3110-3130. DOI： 10.19799/j.cnki.2095-4239.2026.0361.

摘要

随着新能源存储需求的持续增长，水系锌离子电池因其高安全性、低成本及环境友好的优势而备受关注。作为关键正极材料之一，钒基氧化物具有可变的价态、开放的层状结构与较高的理论容量，展现出可观的应用潜力。为进一步提升其电化学性能，构建一维纳米结构（如纳米线、纳米带等）被视为有效策略，可显著改善离子传输效率并缓解循环过程中的体积应变。当前，一维钒基纳米材料在水系锌离子电池中的应用研究不断深入，本文系统梳理其最新进展，重点阐述了非原位和原位技术在Zn

嵌入、转化反应等储能机理中的应用，明确了两种技术在揭示储能本质、优化材料性能中的核心作用；同时总结静电纺丝、水热法等可控制备途径，分析各方法在制备一维钒基纳米材料中的优势与适用性，并探讨离子预嵌、缺陷工程及导电复合等关键优化策略对材料电化学性能的调控作用。最后，针对当前在动力学、结构稳定性及规模化制备方面仍存在的挑战，展望了未来多尺度材料设计与系统集成的研究方向，为推动该体系向实用化发展提供有力支撑。

Abstract

With the continued growth in demand for new energy storage technologies

aqueous zinc-ion batteries have attracted extensive attention because of their high safety

low cost

and environmentally friendly nature. As one of the most important cathode materials

vanadium-based oxides possess variable valence states

open layered structures

and high theoretical capacities

offering promising application prospects. Constructing one-dimensional nanostructures

such as nanowires and nanoribbons

is an effective strategy for further improving electrochemical perfo

rmance

because it can markedly accelerate ion transport kinetics and alleviate volume strain during cycling. Recent research on one-dimensional vanadium-based nanomaterials for aqueous zinc-ion batteries has progressed rapidly; this paper systematically summarizes these latest advances. It focuses on the critical roles of

ex situ

and

in situ

characterization techniques in elucidating energy storage mechanism

including Zn

intercalation and conversion reactions

and optimizing material properties. Meanwhile

the processes

characteristics

and applicability of controllable synthetic routes such as electrospinning and hydrothermal methods are summarized. The effects of ion pre-intercalation

defect engineering

and conductive composite modification on electrochemical behavior are also analyzed. Finally

in view of the existing challenges in reaction kinetics

structural stability

and large-scale preparation

this review proposes future research directions involving multiscale material design and system integration to promote the practical application of aqueous zinc-ion battery systems.

关键词

Keywords

references

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