锂离子电池补锂技术
田孟羽, 詹元杰, 闫勇, 黄学杰

Replenishment technology of the lithium ion battery
Mengyu TIAN, Yuanjie ZHAN, Yong YAN, Xuejie HUANG
图1 卷对卷预锂化方法制备预锂化的LixSnLixAlLixSi/C电极:(a) 卷对卷预锂化示意图;(b) 卷对卷预锂化过程照片;(c) 卷对卷预锂化后的Sn电极(8 cm×16 cm)照片,其中黑色部分为锂化的Li-Sn合金,拥有金属光泽的是未锂化的Sn箔;(d) 预锂化Sn电极截面SEM图,上层为锂化的Li-Sn合金,下层为Sn箔;(ef) 卷对卷预锂化的LixAl箔和LixSi/C极片照片;(g) 卷对卷预锂化的Li-Sn合金箔XRD(h) 预锂化的LixSn箔和纯Sn箔全电池容量和循环测试,蓝色为预锂化LixSn箔,红色为纯Sn[5]
Fig. 1 Roll-to-roll prelithiation method for preparation of LixSn, LixAl and LixSi/C anode electrodes:(a) illustration of roll-to-roll prelithiation method; (b) specific operation of roll-to-roll mechanical prelithiation method; (c) visual image of as-prepared LixSn foil (8 cm×16 cm), where dark layer is Li-Sn alloy and underlay with metallic luster is Sn; (d) cross-sectional SEM image of LixSn alloy foil, where top layer is LixSn and sublayer is pure Sn; (e and f) visual images of as-prepared LixAl foil and LixSi/C, respectively; (g) XRD result of LixSn alloy foil; (h) capacity and cycle stability of LixSn foil and Sn foil in full-cell cycling, The blue symbols represent LixSn and the red ones represent Sn foil[5]