基于无机钠离子导体的固态钠电池研究进展

彭林峰, 贾欢欢, 丁庆, 赵宇明, 谢佳, 程时杰

Research progress of solid-state sodium batteries using inorganic sodium ion conductors

Linfeng PENG, Huanhuan JIA, Qing DING, Yuming ZHAO, Jia XIE, Shijie CHENG

表1 基于氧化物钠离子固态电解质的中低温固态电池总结

Table 1 Summary of solid-state batteries based on oxide sodium solid electrolytes

固态电池 循环圈数 容量保持 温度 参考文献 Na|β?-Al2O3|NaTi3(PO4)3 50圈(0.1 C) 100 mA·h/g RT [25] Na|β?-Al2O3-PVDF-HFP|Na3V2(PO4)3 1000圈（1 C） 90 mA·h/g RT [26] Na|β?-Al2O3|Na0.66Ni0.33Mn0.67O2-IL 10000圈(6 C) 90% 70 ℃ [27] Na|LE-β?-Al2O3-LE|S-C 104圈(1/64 C) 521 mA·h/g RT [28] Na-Sn|β?-Al2O3|PTO-PEO-C 50圈(0.1 C) 80% 60 ℃ [29] Na|β?-Al2O3|NiCl2 350圈(20～30 mA) 355 W·h/kg 190 ℃ [31] Na|CPMEA/Na3Zr2Si2PO12|NaTi2(PO4)3 70圈(0.2 C) 100 mA·h/g 65 ℃ [33] Na|Na3.1Zr1.95Mg0.05Si2PO12|Na0.9Cu0.22Fe0.3Mn0.48O2 100圈(0.5 C) 57.9 mA·h/g RT [35] Na|0.1Ca-NZSP|Na3V2(PO4)3 450(1 C) 94.9 mA·h/g 25 ℃ [36] Na|IL/Na3.3Zr1.7La0.3Si2PO12|Na3V2(PO4)3 10000圈(10 C) 90 mA·h/g RT [39] Na|SN-Na3Zr2Si2PO12|Na3V2(PO4)3 50圈(20 mA/g) 62.23 mA·h/g RT [41] Na|Na3.4Zr2Si2.4P0.6O12|Na3V2(PO4)3 100圈(0.6 C) 96.5 mA·h/g 25 ℃ [42] NVPF|NYSO-PEO-SSE| Na3V2(PO4)3 50圈(1 C) 89% 60 ℃ [45] Na|Na3Zr2Si2PO12|Na2MnFe(CN)6 200圈(0.5 C) 89.2% 60 ℃ [46] Na|CPE-NZMSPO|Na3V2(PO4)3 120圈(0.1 C) 106.1 mA·h/g 80 ℃ [47]