钠离子电池钒基聚阴离子型正极材料的发展现状与应用挑战
易红明, 吕志强, 张华民, 宋明明, 郑 琼, 李先锋

Recent progress and application challenges in V-based polyanionic compounds for cathodes of sodium-ion batteries
Hongming YI, Zhiqiang LYU, Huamin ZHANG, Mingming SONG, Qiong ZHENG, Xianfeng LI
图4 (a) Na3V2(PO4)2F3的晶体结构,绿色双八面体为V2O8F3,黄色四面体为PO4(b) Na3V2(PO4)2F3的充放电曲线;
(c)(d) Na3V2(PO4)2F3的原位SXRD
Fig.4 (a) crystal structure of Na3V2(PO4)2F3, bioctahedral V2O8F3 (green) and tetrahedral PO4 (yellow) building blocks are showed; (b) charge/discharge profiles of Na3V2(PO4)2F3; (c)(d) in situ SXRD of Na3V2(PO4)2F3