化学热泵系统在储热技术中的理论与应用

doi:10.3969/j.issn.2095-4239.2014.03.007

摘要/Abstract

摘要： 化学热泵是高效,环保的新型能源技术,在余热回收,储热,可再生能源等领域具有广泛的应用前景.本文综述了化学热泵系统的一般理论和在储热技术中的应用,介绍了化学热泵系统技术在反应与工质对选择,传热强化以及工业研究与应用等方面的发展.

关键词: 化学热泵, 储能, 储热, 传热, 可再生能源

Abstract: Chemical heat pump (CHP) is a high-efficient and environment-friendly energy technology. CHP has promising potential on applications in waste-heat harvest, energy storage and renewable energy. This paper reviews the general theory and application progress in terms of the reaction selection, working pairs and industrial development.

Key words: chemical heat pump (CHP), energy storage, thermal energy storage (TES), heat transfer, renewable energy

中图分类号:

TM911

宋鹏翔, 丁玉龙. 化学热泵系统在储热技术中的理论与应用[J]. 储能科学与技术, 2014, 3(3): 227-235.

SONG Pengxiang, DING Yulong. A review on theory and application of chemical heat pump in thermal energy storage[J]. Energy Storage Science and Technology, 2014, 3(3): 227-235.

参考文献

[1] Zou Shengou(邹盛欧). 节能设备化学热泵技术[J]. Chemical Eqiupment Technology (化工装备技术),1995(2):28-33.
[2] Zou Shengou(邹盛欧). 化学热泵的开发与应用[J]. Petrochemical Technology (石油化工),1996,25(4):294-299.
[3] Paksoy H Ö. Thermal Energy Storage for Sustainable Energy Consumption[M]. New York:Springer,2007.
[4] Huang Hui(黄辉),Li Qi(李奇),Qiu Weiwei(邱伟伟). Application of renewable energy in surface engineering of oil field[J]. Energy Conservation in Petroleum & Petrochemical Industry (石油石化节能),2013(6):63-66.
[5] Lin Guiping(林贵平),Yuan Xiugan(袁修干). 化学热泵系统研究[J]. Journal of Aerospace Power (航空动力学报),1995,10(1):57-58.
[6] Lin Guiping(林贵平),Yuan Xiugan(袁修干). Application of chemical heat pump systems to the thermal utilization of solar energy[J]. Acta Energiae Solaris Sinica (太阳能学报),1996, 17(1):93-97.
[7] Wongsuwan W,Kumar S,Neveu P,Meunier F. A review of chemical heat pump technology and applications[J]. Applied Thermal Engineering ,2001,21(15):1489-1519.
[8] Kato Y,Takahashi F,Watanabe A,Yoshizawa Y. Thermal performance of a packed bed reactor of a chemical heat pump for cogeneration[J]. Chemical Engineering Research and Design , 2000,78(5):745-748.
[9] Li Aiju(李爱菊),Zhang Renyuan(张仁元),Zhou Xiaoxia(周晓霞). Progress of research on chemical energy storage materials[J]. Journal of Guangdong University of Technology (广东工业大学学报),2003,19(1):81-84.
[10] Wu Huijun(吴会军),Zhu Dongsheng(朱冬生),Li Jun(李军),Wang Chunhua(王春华),Cheng Jun(程军). Research progress on thermal energy storage material[J]. Materials Review (材料导报),2005,19(8):96-98.
[11] Groll M,Isselhorst A,Wierse M. Metal hydride devices for environmentally clean energy technology[J]. International Journal of Hydrogen Energy ,1994,19(6):507-515.
[12] Muthukumar P,Groll M. Metal hydride based heating and cooling systems:A review[J]. International Journal of Hydrogen Energy ,2010,35(8):3817-3831.
[13] Reiser A,Bogdanović B,Schlichte K. The application of Mg-based metal-hydrides as heat energy storage systems[J]. International Journal of Hydrogen Energy ,2000,25(5): 425-430.
[14] Satya Sekhar B,Muthukumar P,Saikia R. Tests on a metal hydride based thermal energy storage system[J]. International Journal of Hydrogen Energy ,2012,37(4):3818-3824.
[15] Sheppard D A,Paskevicius M,Buckley C E. Thermodynamics of hydrogen desorption from NaMgH 3 and its application as a solar heat storage medium[J]. Chemistry of Materials ,2011,23(19): 4298-4300.
[16] Wierse M,Werner R,Groll M. Magnesium hydride for thermal energy storage in a small-scale solar-thermal power station[J]. Journal of the Less Common Metals ,1991,172-174(3): 1111-1121.
[17] Bao Zewei(鲍泽威),Wu Zhen(吴震),Nyallang Nyamsi Serge,Yang Fusheng(杨福胜),Zhang Zaoxiao(张早校). Progress of high temperature heat storage technology using metal hydrides[J]. Chemical Industry and Engineering Progress (化工进展),2012,31(8):1665-1676.
[18] Yang F S,Wang G X,Zhang Z X,Meng X Y,Rudolph V. Design of the metal hydride reactors A review on the key technical issues[J]. International Journal of Hydrogen Energy ,2010, 35(8):3832-3840.
[19] E.ON International Research Initiative. Global funding for new energy technologies[EB/OL]. https://www.eon.com/en/careers/students- and-graduates/cooperation-and-scientific-support/international-research- initiative.html.
[20] Kato Y,Takahashi F,Watanabe A,Yoshizawa Y. Thermal analysis of a magnesium oxide/water chemical heat pump for cogeneration[J]. Applied Thermal Engineering ,2010,21(10): 1067-1081.
[21] Spoelstra S,Haije W G,Dijkstra J. Techno-economic feasibility of high-temperature high-lift chemical heat pumps for upgrading industrial waste heat[J]. Applied Thermal Engineering ,2002, 22(14):1619-1630.
[22] Zuo Yuanzhi(左远志),Ding Jing(丁静),Yang Xiaoxi(杨晓西). Current status of thermal energy storage technologies used for concentrating solar power systems[J]. Chemical Industry and Engineering Progress (化工进展),2006,25(9):995-1000,1030.
[23] Yang Xiaoping(杨小平),Yang Xiaoxi(杨晓西),Ding Jing(丁静),Yang Minlin(杨敏林). Recent advances in the study of solar energy high-temperature heat power generation and accumulation technologies[J]. Journal of Engineering for Thermal Energy and Power (热能动力工程),2011,26(1):1-6.
[24] Lovegrove K,Luzzi A. Endothermic reactors for an ammonia based thermochemical solar energy storage and transport system[J]. Solar Energy ,1996,56(4):361-371.
[25] Ito S,Nishikawa M,Miura N,Wang J Q. Heat pump using a solar collector with photovoltaic modules on the surface[J]. Journal of Solar Energy Engineering ,1997,119(2):147-151.
[26] Friedlmeier G,Wierse M,Groll M. Titanium hydride for high-temperature thermal energy storage in solar-thermal power stations[J]. Zeitschrift für Physikalische Chemie ,1994,183(12):175-175.
[27] Zhao Haibo(赵海波),Wu Kun(吴坤). Heat pump and air-conditioning systems driven by wind energy[J]. Building Energy & Environment (建筑热能通风空调),2010,29(1):32-35.
[28] Long Hongyu(龙虹毓),Ma Jianwei(马建伟),Wu Kai(吴锴),Yang Yulong(杨玉龙),Zhang Jingbo(张竞博),Su Ling(苏岭),Chou Bin(仇斌). Energy conservation dispatch of power grid with mass cogeneration and wind turbines[J]. Electric Power Automation Equipment (电力自动化设备),2011,31(11):18-22.
[29] Kato Y,Saku D,Harada N,Yoshizawa Y. Utilization of high temperature heat using a calcium oxide/lead oxide/carbon dioxide chemical heat pump[J]. J. Chem. Eng. Japan ,1997,30(6): 1013-1019.
[30] Li Y,Cao H,Wang S,Jin Y,Li D,Wang X,Ding Y. Load shifting of nuclear power plants using cryogenic energy storage technology[J]. Applied Energy ,2014,113:1710-1716.
[31] Tae K S,Ryu J,Kato Y. Reactivity enhancement of chemical materials used in packed bed reactor of chemical heat pump[J]. Progress in Nuclear Energy ,2011,53(7):1027-1033.
[32] Chan CW,Ling-Chin J,Roskilly A P. A review of chemical heat pumps,thermodynamic cycles and thermal energy storage technologies for low grade heat utilization[J]. Applied Thermal Engineering ,2013,50:1257-1273.
[33] Zamengo M,Ryu J,Kato Y. Thermochemical performance of magnesium hydroxide-expanded graphite pellets for chemical heat pump[J]. Applied Thermal Engineering ,2014,64(1-2):339-347.
[34] Guo J,Huai X. Optimization design of recuperator in a chemical heat pump system based on entransy dissipation theory[J]. Energy ,2012,41(1):335-343.
[35] Yurtsever A O,Karakas G,Uludag Y. Modeling and computational simulation of adsorption based chemical heat pumps[J]. Applied Thermal Engineering , 2013,50(1):401-407.