锂电池研究中的循环伏安实验测量和分析方法

doi:10.12028/j.issn.2095-4239.2018.0067

储能科学与技术 ›› 2018, Vol. 7 ›› Issue (3): 539-553.doi: 10.12028/j.issn.2095-4239.2018.0067

• 储能标准与规范 • 上一篇

锂电池研究中的循环伏安实验测量和分析方法

聂凯会, 耿振, 王其钰, 岳金明, 禹习谦, 李泓

中国科学院物理研究所, 北京 100190

收稿日期:2018-04-02 修回日期:2018-04-14 出版日期:2018-05-01 发布日期:2018-05-01
通讯作者: 李泓,研究员,研究方向为高能量密度锂离子电池,固态电池及失效分析,E-mail:hli@iphy.ac.cn
作者简介:聂凯会(1994-),女,硕士研究生,研究方向为锂离子电池层状正极材料的高电压行为与优化,以及锂电池失效分析,E-mail:niekaihui12138@163.com
基金资助:
国家重点研发计划（2016YFB0100300，2016YFB0100100）以及中国科学院战略性先导科技专项（XDA09010000）。

Experimental measurement and analysis methods of cyclic voltammetry for lithium batteries

NIE Kaihui, GENG Zhen, WANG Qiyu, YUE Jinming, YU Xiqian, LI Hong

Institute of Physics, Chinese Academy of Sciences, Beijing 100190, China

Received:2018-04-02 Revised:2018-04-14 Online:2018-05-01 Published:2018-05-01

摘要/Abstract

摘要： 循环伏安作为一种重要的电化学测试方法，在电化学领域尤其是锂电池的研究中有着广泛的应用，常用于电极反应可逆性、电极反应机理及电极反应动力学参数的研究。本文介绍了循环伏安的基本原理、测试方法以及常用仪器，并结合实际案例，具体分析了循环伏安在锂电池电极材料反应机理、电极过程动力学以及电解液电化学稳定性方面的应用研究。

关键词: 循环伏安法, 测试方法, 电化学, 锂电池

Abstract: Cyclic voltammetry (CV) is a very important electrochemical measurement method, which has been widely used in electrochemistry research especially for the study of lithium batteries. CV is commonly used to study the reversibility, mechanism and kinetic properties of electrode reactions in lithium batteries. Here, we overviewed the fundamental principles, experimental methods and the commonly used equipments for the CV measurement. Besides, its applications on the study of lithium batteries were introduced in detail, combing with practical experimental cases.

Key words: cyclic voltammetry, measurement method, electrochemistry, lithium batteries

中图分类号:

TM911

聂凯会, 耿振, 王其钰, 岳金明, 禹习谦, 李泓. 锂电池研究中的循环伏安实验测量和分析方法[J]. 储能科学与技术, 2018, 7(3): 539-553.

NIE Kaihui, GENG Zhen, WANG Qiyu, YUE Jinming, YU Xiqian, LI Hong. Experimental measurement and analysis methods of cyclic voltammetry for lithium batteries[J]. Energy Storage Science and Technology, 2018, 7(3): 539-553.

参考文献

[1] BARD A J, FAULKNER L R. Electrochemical methods:Fundamentals and applications[M]. New York:Wiley, 1980.
[2] PARk J K. Principles and applications of lithium secondary batteries[M]. New York:John Wiley & Sons, 2012.
[3] FUJISHIMA A. Electrochemical method:Various chemical sensors[J]. Bulletin of the Society of Sea Water Science Japan, 1989, 43:200-207.
[4] 蒲国刚,袁倬斌,吴守国. 电分析化学[M]. 合肥:中国科学技术大学出版社, 1993. PU G G, YUAN Z B, WU S G. Electrochemical analysis[M]. Hefei:Science and Technology of China Press, 1993.
[5] SAUVAGE F, BAUDRIN E, MORCRETTE M, et al. Pulsed laser deposition and electrochemical properties of LiFePO₄ thin films[J]. Electrochemical and Solid State Letters, 2004, 7(1):A15-A18.
[6] XU Q, ZHAO T S, WEI L, et al. Electrochemical characteristics and transport properties of Fe(Ⅱ)/Fe(Ⅲ) redox couple in a non-aqueous reline deep eutectic solvent[J]. Electrochimica Acta, 2015, 154:462-467.
[7] WANG S P, LIU Q L, YU J X, et al. Anisotropic expansion and high rate discharge performance of V-doped MnO₂ for Li/MnO₂ primary battery[J]. International Journal of Electrochemical Science, 2012, 7(2):1242-1250.
[8] 王其钰, 褚赓, 张杰男, 等. 锂离子扣式电池的组装, 充放电测试和数据分析[J]. 储能科学与技术, 2018, 7(2):327-344. WANG Q Y, CHU G, ZHANG J N, et al. The assembly, charge-discharge performance measurement and data analysis of lithium-ion button cell[J].Energy Storage Science and Technology, 2018, 7(2):327-344.
[9] VASSILIEV S Y, LEVIN E E, NIKITINA V A. Kinetic analysis of lithium intercalating systems:Cyclic voltammetry[J]. Electrochimica Acta, 2016, 190:1087-1099.
[10] DOLLÉ M l, ORSINI F o, GOZDZ A S, et al. Development of reliable three-electrode impedance measurements in plastic Li-ion batteries[J]. Journal of The Electrochemical Society, 2001, 148(8):A851.
[11] LI H, HUANG X J, CHEN L Q, Anodes based on oxide materials for lithium rechargeable batteries[J]. Solid State Ionics, 1999, 123(1-4):189-197.
[12] LI H, ZHU G Y, HUANG X J, et al. Synthesis and electrochemical performance of dendrite-like nanosized Sn Sb alloy prepared by co-precipitation in alcohol solution at low temperature[J]. Journal of Materials Chemistry, 2000, 10(3):693-696.
[13] HANSEN S, QUIROGA-GONZALEZ E, CARSTENSEN J, et al. Size-dependent cyclic voltammetry study of silicon microwire anodes for lithium ion batteries[J]. Electrochimica Acta, 2016, 217:283-291.
[14] OPITZ M, YUE J P, WALLAUER J, et al. Mechanisms of charge storage in nanoparticulate TiO₂ and Li₄Ti₅O₁₂ anodes:New insights from scan rate-dependent cyclic voltammetry[J]. Electrochimica Acta, 2015, 168:125-132.
[15] PELED E, GORENSHTEIN A, SEGAL M, et al. Rechargeable lithium sulfur battery[J]. Journal of Power Sources, 1989, 26(3/4):269-271.
[16] JEON B H, YEON J H, KIM K M, et al. Preparation and electrochemical properties of lithium-sulfur polymer batteries[J]. Journal of Power Sources, 2002, 109(1):89-97.
[17] WU F, CHEN J Z, CHEN R J, et al. Sulfur/polythiophene with a core/shell structure:Synthesis and electrochemical properties of the cathode for rechargeable lithium batteries[J]. Journal of Physical Chemistry C, 2011, 115(13):6057-6063.
[18] YIN Y X, XIN S, GUO Y G, et al. Lithium-sulfur batteries:Electrochemistry, materials, and prospects[J]. Angewandte Chemie-International Edition, 2013, 52(50):13186-13200.
[19] WAN D Y, FAN Z Y, DONG Y X, et al. Effect of metal (Mn, Ti) doping on NCA cathode materials for lithium ion batteries[J]. Journal of Nanomaterials, 2018.
[20] ROUGIER A, STRIEBEL K A, WEN S J, et al. Cyclic voltammetry of pulsed laser deposited LixMn₂O₄ thin films[J]. Journal of the Electrochemical Society, 1998, 145(9):2975-2980.
[21] REDDY M V, PECQUENARD B, VINATIER P, et al. Cyclic voltammetry and galvanostatic cycling characteristics of LiNiVO₄ thin films during lithium insertion and re/de-insertion[J]. Electrochemistry Communications, 2007, 9(3):409-415.
[22] HASHAMBHOY A M, WHITACRE J F. Li Diffusivity and phase change in LiFe_0.5Mn_0.5PO₄:A comparative study using galvanostatic intermittent titration and cyclic voltammetry[J]. Journal of the Electrochemical Society, 2011, 158(4):A390-A395.
[23] XIE J, IMANISHI N, HIRANO A, et al. Kinetics investigation of a preferential (104) plane oriented LiCoO₂ thin film prepared by RF magnetron sputtering[J]. Solid State Ionics, 2007, 178(19/20):1218-1224.
[24] YU D Y W, FIETZEK C, WEYDANZ W, et al. Study of LiFePO₄ by cyclic voltammetry[J]. Journal of the Electrochemical Society, 2007, 154(4):A253-A257.
[25] 凌世刚, 吴娇杨, 张舒, 等. 锂离子电池基础科学问题(Ⅷ)-电化学测量方法[J]. 储能科学与技术, 2015, 4(1):83-103 LING S G, WU J Y, ZHANG S, et al. Fundamental scientific aspects of lithium ion batteries(Ⅷ)-Electrochemical measurements[J]. Energy Storage Science and Technology, 2015, 4(1):83-103
[26] TANG S B, LAI M O, LU L. Li-ion diffusion in highly (003) oriented LiCoO₂ thin film cathode prepared by pulsed laser deposition[J]. Journal of Alloys and Compounds, 2008, 449(1/2):300-303.
[27] Tang K, Yu X Q, Sun J P, et al. Kinetic analysis on LiFePO₄ thin films by CV, GITT, and EIS[J]. Electrochimica Acta, 2011, 56:4869-4875.
[28] RUI X H, DING N, LIU J, et al. Analysis of the chemical diffusion coefficient of lithium ions in Li₃V₂(PO₄)₃ cathode material[J]. Electrochimica Acta, 2010, 55(7):2384-2390.
[29] DING N, XU J, YAO Y X, et al. Determination of the diffusion coefficient of lithium ions in nano-Si[J]. Solid State Ionics, 2009, 180(2/3):222-225.
[30] RHO Y H, KANAMURA K. Li⁺ ion diffusion in Li₄Ti₅O₁₂ thin film electrode prepared by PVP sol-gel method[J]. Journal of Solid State Chemistry, 2004, 177(6):2094-2100.
[31] XU W, CHEN X L, DING F, et al. Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications[J]. Journal of Power Sources, 2012, 213:304-316.
[32] REDDY V P, SMART M C, CHIN K B, et al.[sup 13] C NMR spectroscopic, CV, and conductivity studies of propylene carbonate-based electrolytes containing various lithium salts[J]. Electrochemical and Solid-State Letters, 2005. 8(6):A294.
[33] 周思思. 关于锂盐LiFSI与LiFNFSI的电解液研究[D]. 北京:中国科学院大学, 2012.
[34] CHEN X L, XU W, ENGELHARD M H, et al. Mixed salts of LiTFSI and LiBOB for stable LiFePO₄-based batteries at elevated temperatures[J]. Journal of Materials Chemistry A, 2014, 2(7):2346-2352.
[35] LI Y X, ZHANG X W, KHAN S A, et al. Attenuation of aluminum current collector corrosion in LiTFSI electrolytes using fumed silica nanoparticles[J]. Electrochemical and Solid State Letters, 2004, 7(8):A228-A230.

锂电池研究中的循环伏安实验测量和分析方法

Experimental measurement and analysis methods of cyclic voltammetry for lithium batteries

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