储能科学与技术 ›› 2018, Vol. 7 ›› Issue (3): 365-375.doi: 10.12028/j.issn.2095-4239.2018.0018

• 高比能量动力锂离子电池专刊 • 上一篇    下一篇

钾离子电池关键材料的研究进展

李文挺1,2,3, 安胜利2,3,4, 邱新平1   

  1. 1. 清华大学化学系, 北京 100084;
    2. 北京科技大学冶金与生态学院, 北京 100083;
    3. 内蒙古科技大学材料与冶金学院, 内蒙古 包头 014010;
    4. 鄂尔多斯应用技术学院, 内蒙古 鄂尔多斯 017000
  • 收稿日期:2018-02-03 修回日期:2018-03-21 出版日期:2018-05-01 发布日期:2018-05-01
  • 通讯作者: 邱新平,教授,主要从事锂离子电池、直接醇燃料电池及储能电堆为主的先进化学电源的基础及应用研究,E-mail:qiuxp@mail.tsinghua.edu.cn
  • 作者简介:李文挺(1990-),男,博士研究生,主要研究方向为钾离子电池功能材料,E-mail:liwenting@mail.tsinghua.edu.cn
  • 基金资助:
    国家重点研发计划项目（2016YFB0901703）。

Research on key materials for potassium ion batteries

LI Wenting1,2,3, AN Shengli2,3,4, QIU Xinping1   

  1. 1. Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing 100084, China;
    2. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Beijing 100083, China;
    3. School of Material and Metallurgy, Inner Mongolia University of Science and Technology, Baotou 014010, Inner Mongolia, China;
    4. Ordos Insititute of Technology, Ordos 017000, Inner Mongolia, China
  • Received:2018-02-03 Revised:2018-03-21 Online:2018-05-01 Published:2018-05-01

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被引次数

1

摘要： 钾具有资源丰富、价格低廉以及较低的电化学电势的特点，利用其开发的钾离子电池具有低成本、长寿命、能量密度高等特点，可满足储能领域需要。然而，钾离子半径大和质量大，给电池电极材料与电解质材料开发提出新的挑战。近年来，在电动汽车与储能应用等重大需求的牵引下，人们对钾离子电池的高容量电极材料和电解液进行了大量的研究工作。其中普鲁士蓝及其类似物、过渡金属氧化物和聚阴离子材料等正极材料展现了应用前景；负极材料主要包括碳基、钛基和合金类材料；电解质材料有酯类电解质和醚类电解质，这些研究成果为钾离子电池的基础与应用研究提供了重要的指导意义。

关键词: 钾离子电池, 正极材料, 负极材料, 电解质

Abstract: Potassium ion batteries can meet the requirements of energy storage system owing to their advantages of low cost, long life and high energy density, since potassium is the element with abundant resource, low price and low electrochemical potential. However, challenges coming from disadvantages of larger and heavier of potassium ion still confront of the development of electrode materials and electrolyte for potassium ion batteries. In recent years, the high capacity electrode materials and electrolyte of potassium ion batteries have been studied extensively under the traction of electric vehicles and energy storage applications. The cathode materials such as Prussian blue and its analogues, transition metal oxides and polyanionic materials show the application prospect. Available anode materials consist of carbon, titanium and alloy materials. Effective electrolytes involve ester-based electrolytes and ether-based electrolytes. These results are significant for the basic and applied research of potassium ion batteries.

Key words: potassium ion batteries, cathode, anode, electrolyte

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